The playable teaser of this year's instalment can be downloaded from Xbox 360 and PC, while the PS3 version is scheduled for 5pm.
Announced last week, it offers eight licensed teams, including international sides Germany, England, Portugal and Italy, as well as club teams Santos FC, SC International, Fluminense and Flamengo.
The demo will showcase a number of changes coming to this year's title, including FullControl for improved control options over every pass, shot and first touch.
Gallery - view screenshots from PES 2013's demo below:
Dribbling, meanwhile, has been slowed for the new game, giving players better close-control of the ball, allowing them to hold it up within a 360-degree circle, or nutmeg opposing players and run onto the loose ball.
PES 2013 releases this autumn for the Xbox 360, PS3, PC, PS2, PSP, Nintendo 3DS and Wii. A PlayStation Vita version was recently ruled out by Konami.
> Read our PES 2012 review
Watch the latest gameplay trailer for PES 2013 below: