James Bond (Craig) is seen waiting at London's National Gallery in the new picture from the upcoming action thriller from Sam Mendes.
Omega has also released photos of the official Skyfall watch.
Seamaster Planet Ocean 600M "Skyfall" Limited Edition will see a limited release of just 5,007 watches available for purchase.
Craig will be seen wearing the Swiss watch in the film. It has a 42mm stainless steel case and a matte black ceramic rotating bezel, matching dial and chromium nitride diving scale.
The timepiece also comes in white Super-LumiNova, while the hands and dial emit a blue light, with the minute hand and diving bezel glowing green.
Javier Bardem, Ralph Fiennes, Ben Whishaw, Bérénice Marlohe and Naomie Harris co-star in Skyfall, opening in cinemas and IMAX screens on October 26 in the UK and November 9 in the US.
Watch the trailer for Skyfall below:
In pictures: Daniel Craig returns as James Bond in Skyfall