The Chic musician revealed he was working with the French electronic duo earlier this year.
The producer explained that the collaboration is among the best of his long career, which has seen him work with the likes of Madonna, Duran Duran, Diana Ross and Grace Jones.
"All I can say is those guys are geniuses and to think that after all these years we've been trying to get together, they just show up at my apartment in New York City and the vibe between us is so powerful and so strong – it's unbelievable," he told Mixmag.
He added: "Spiritually and artistically working with them was as good as anything I've ever done. It's as great as being in a studio with Bowie, it's as great as being with Bernard Edwards, and it's as great as the best stuff I've ever done with [Duran] Duran and Madonna."
Daft Punk are currently working on their first studio album since 2005's Human After All, and their first release since the 2010 soundtrack to Tron: Legacy.
They were recently rumoured to be releasing a new single named 'Renoma Street' last month, but this was later revealed to be a hoax.
Nile Rodgers is also working with La Roux on their upcoming second album.